N-heterocyclic carbene-initiated hydrosilylation of styryl alcohols with dihydrosilanes: a mechanistic investigation.

نویسندگان

  • David Gatineau
  • Qiwu Zhao
  • Dennis P Curran
  • Max Malacria
  • Emmanuel Lacôte
  • Louis Fensterbank
  • Jean-Philippe Goddard
چکیده

Investigation of the mechanism of the NHC-initiated hydrosilylation of styryl alcohols in the presence of a dihydrosilane suggests a general base catalysis mechanism and not the activation of the dihydrosilane by the NHC.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Highly efficient catalytic hydrosilylation of carbon dioxide by an N-heterocyclic carbene copper catalyst.

The N-heterocyclic carbene-copper alkoxide complex [(IPr)Cu(OtBu)] acts as a highly efficient catalyst for the hydrosilylation of carbon dioxide with a hydrosilane. The desired product, silyl formate could be isolated in multigram quantity under solvent free conditions. A copper formate catalyst intermediate was successfully isolated and structurally characterized, thus offering important insig...

متن کامل

Synthesis of novel axially chiral Rh-NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones.

Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1'-binaphthalenyl-2,2'-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee.

متن کامل

Rhodium carbene complexes as versatile catalyst precursors for Si-H bond activation.

Rhodium(III) complexes comprising monoanionic C,C,C-tridentate dicarbene ligands activate Si-H bonds and catalyse the hydrolysis of hydrosilanes to form silanols and siloxanes with concomitant release of H(2). In dry MeNO(2), selective formation of siloxanes takes place, while changing conditions to wet THF produces silanols exclusively. Silyl ethers are formed when ROH is used as substrate, th...

متن کامل

Regioselective allene hydrosilylation catalyzed by N-heterocyclic carbene complexes of nickel and palladium.

Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by the choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene (NHC) ligands, and allylsilanes are produced via palladium catalysis with smaller NHC ligands. These complementary methods allow either regioisomeric product to be obtaine...

متن کامل

Dendrimer N-heterocyclic carbene complexes with rhodium(I) at the core.

Novel dendrimer N-heterocyclic carbene complexes with rhodium(I) located at the core were synthesized, and a positive dendrimer effect was found in the hydrosilylation of ketones catalyzed by them.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Dalton transactions

دوره 42 20  شماره 

صفحات  -

تاریخ انتشار 2013